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 Australian shrub contains new class of organic compoundThe botanical world can be an exciting place

Australian shrub contains new class of organic compound

The botanical world can be an exciting place for chemists. Plant species produce a beautiful array of organic molecules with complex structures, often of great practical use. Indeed, this is a realm where new discoveries are still being made. Recently, a Japanese-led research team discovered an entirely new structural class in compounds from a jungle-dwelling shrub.

The glossy or red-fruited laurel (binomial name: Cryptocarya laevigata) inhabits the rainforests of eastern Australia. Little was known about the chemical makeup of this tall shrub until the team, led by Kanazawa University, analyzed an extract of its twigs and leaves. The plant’s essential oil was found to contain a family of six new compounds, the structural analysis of which revealed some surprises.

As reported in Organic Letters, NMR experiments showed that at the center of the compounds lay a peculiar, nine-membered carbon cycle known as a spiro-nonene. This structure consists of two rings of carbon atoms—one containing six atoms, the other four—linked by a single “pinch point” atom that is a part of both rings. This motif had never been seen before in any natural product.

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SOAK UP THE SUN - @adelaidekane WEARING THE KIT BIKINI TOP & BOTTOM IN OUR PRINT IN COLLABORATIO

SOAK UP THE SUN - @adelaidekane WEARING THE KIT BIKINI TOP & BOTTOM IN OUR PRINT IN COLLABORATION WITH @theline_ ⠀
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#bikini #holiday #newyears #australia #home (at Eagle Bay, Dunsborough)
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Sutherland Leisure Centre, Sydney, Australia

Sutherland Leisure Centre, Sydney, Australia


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Ian Thorpe Aquatic Centre, Sydney, AustraliaIan Thorpe Aquatic Centre, Sydney, Australia

Ian Thorpe Aquatic Centre, Sydney, Australia


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Turtle-headed sea snake - Emydocephalus annulatus (Image credit: University of Adelaide)

Turtle-headed sea snake - Emydocephalus annulatus

(Image credit: University of Adelaide)


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Stokes’ sea snake - Hydrophis stokesiiPhotographer: Christopher Watson

Stokes’ sea snake - Hydrophis stokesii

Photographer: Christopher Watson


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Horned sea snake - Hydrophis peroniiPhotographer: JurgenxFreund

Horned sea snake - Hydrophis peronii

Photographer: JurgenxFreund


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Olive sea snake - Aipysurus laevis (Image credit: Gabriel Guzman)

Olive sea snake - Aipysurus laevis

(Image credit: Gabriel Guzman)


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Small-headed sea snake - Hydrophis macdowelliPhotographer: iNaturalistUK

Small-headed sea snake - Hydrophis macdowelli

Photographer: iNaturalistUK


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Leaf-scaled sea snake - Aipysurus foliosquama (Image credit: Hal Cogger)

Leaf-scaled sea snake - Aipysurus foliosquama

(Image credit: Hal Cogger)


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Dubois’ sea snake - Aipysurus duboisiiPhotographer: Chris Cooper

Dubois’ sea snake - Aipysurus duboisii

Photographer: Chris Cooper


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 Olive sea snake - Aipysurus laevis Image credit: indianoceanimagery/Getty

Olive sea snake - Aipysurus laevis

Image credit: indianoceanimagery/Getty


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